Can people throw in some opinions about hard hot starting versus fuel composition?
Occasionally someone will remark about ethanol in modern automotive fuel leading to hard hot starts. There may also be a remark about ethanol having a low boiling point which contributes to hard hot start problems.
Gasoline typically is a mix of pentanes (boiling point around 36 deg C), hexanes (boiling point 68 deg C), heptanes (boiling point 98 deg C), thousands of other carbon compounds, and nowadays ethanol (boiling point 78 deg C). I can find literature which shows gasoline boils starting at 39 deg C, with the boiling point rising as the distillation clears out the lower boiling point elements, reaching boiling point of 110 deg C at 50% distillation.
Vapor pressure versus temperature curves can be found showing ethanol-free gasoline has a higher vapor pressure than ethanol until reaching ethanol boiling point. I also have the impression that vapor lock issues are reduced in racing conditions when using alcohol fuels. And finally on vapor pressure, don’t fuel suppliers vary the gasoline vapor pressure with the season, so a car rarely driven could have a high vapor pressure winter blend in use on a hot summer day?
Both the boiling point temperatures and the vapor pressures suggest that ethanol reduces hard hot start problems resulting from vapors compared to gasoline without ethanol.
What are your observations? What sources of evidence can help understand whether ethanol blend fuels create harder hot start problems than ethanol-free gasoline?